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Volume 13, issue 12 | Copyright
Clim. Past, 13, 1815-1830, 2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 13 Dec 2017

Research article | 13 Dec 2017

Analytical constraints on layered gas trapping and smoothing of atmospheric variability in ice under low-accumulation conditions

Kévin Fourteau1, Xavier Faïn1, Patricia Martinerie1, Amaëlle Landais2, Alexey A. Ekaykin3, Vladimir Ya. Lipenkov3, and Jérôme Chappellaz1 Kévin Fourteau et al.
  • 1Univ. Grenoble Alpes, CNRS, IRD, Grenoble INP, IGE, 38000 Grenoble, France
  • 2Laboratoire des Sciences du Climat et de l'Environnement, UMR8212, CEA-CNRS-UVSQ-UPS/IPSL, Gif-sur-Yvette, France
  • 3Climate and Environmental Research Laboratory, Arctic and Antarctic Research Institute, St. Petersburg, 199397, Russia

Abstract. We investigate for the first time the loss and alteration of past atmospheric information from air trapping mechanisms under low-accumulation conditions through continuous CH4 (and CO) measurements. Methane concentration changes were measured over the Dansgaard–Oeschger event 17 (DO-17,  ∼  60 000 yr BP) in the Antarctic Vostok 4G-2 ice core. Measurements were performed using continuous-flow analysis combined with laser spectroscopy. The results highlight many anomalous layers at the centimeter scale that are unevenly distributed along the ice core. The anomalous methane mixing ratios differ from those in the immediate surrounding layers by up to 50 ppbv. This phenomenon can be theoretically reproduced by a simple layered trapping model, creating very localized gas age scale inversions. We propose a method for cleaning the record of anomalous values that aims at minimizing the bias in the overall signal. Once the layered-trapping-induced anomalies are removed from the record, DO-17 appears to be smoother than its equivalent record from the high-accumulation WAIS Divide ice core. This is expected due to the slower sinking and densification speeds of firn layers at lower accumulation. However, the degree of smoothing appears surprisingly similar between modern and DO-17 conditions at Vostok. This suggests that glacial records of trace gases from low-accumulation sites in the East Antarctic plateau can provide a better time resolution of past atmospheric composition changes than previously expected. We also developed a numerical method to extract the gas age distributions in ice layers after the removal of the anomalous layers based on comparison with a weakly smoothed record. It is particularly adapted for the conditions of the East Antarctic plateau, as it helps to characterize smoothing for a large range of very low-temperature and low-accumulation conditions.

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Short summary
We measured methane concentrations from a polar ice core to quantify the differences between the ice record and the past true atmospheric conditions. Two effects were investigated by combining data analysis and modeling: the stratification of polar snow before gas enclosure driving chronological hiatuses in the record and the gradual formation of bubbles in the ice attenuating fast atmospheric variations. This study will contribute to improving future climatic interpretations from ice archives.
We measured methane concentrations from a polar ice core to quantify the differences between the...