Articles | Volume 16, issue 1
https://doi.org/10.5194/cp-16-17-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-16-17-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Jan 2020
Research article |
| 07 Jan 2020
| 07 Jan 2020
Experimental evaluation of oxygen isotopic exchange between inclusion water and host calcite in speleothems
Graduate School of Environmental Studies, Nagoya University,
Furo-cho, Chikusa-ku, Nagoya, 464-8601, Japan
Yudai Kina
Department of Chemistry, Biology, and Marine Science, Faculty of
Science, University of the Ryukyus, 1 Senbaru, Nishihara, Okinawa, 903-0213,
Japan
Chuan-Chou Shen
High-Precision Mass Spectrometry and Environment Change Laboratory
(HISPEC), Department of Geosciences, National Taiwan University, Taipei
10617, Taiwan
Research Center for Future Earth, National Taiwan University, Taipei
10617, Taiwan
Global Change Research Center, National Taiwan University, Taipei
10617, Taiwan
Kanako Omine
Department of Chemistry, Biology, and Marine Science, Faculty of
Science, University of the Ryukyus, 1 Senbaru, Nishihara, Okinawa, 903-0213,
Japan
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Cited
18 citations as recorded by crossref.
- Characterization and Correction of Evaporative Artifacts in Speleothem Fluid Inclusion Isotope Analyses as Applied to a Stalagmite From Borneo A. Fernandez et al. 10.1029/2023GC010857
- Variability in effective moisture inferred from inclusion fluid δ18O and δ2H values in a central Sierra Nevada stalagmite (CA) B. Wortham et al. 10.1016/j.quascirev.2022.107399
- A geochemical study of the Sweet Home mine, Colorado Mineral Belt, USA: formation of deep hydrothermal vein–type molybdenum greisen and base metal mineralization M. Stoltnow et al. 10.1007/s00126-022-01102-6
- Oxygen isotopes of the Japanese stalagmites as global and local paleoclimate proxies A. Kano et al. 10.1111/iar.12491
- Last glacial temperature reconstructions using coupled isotopic analyses of fossil snails and stalagmites from archaeological caves in Okinawa, Japan R. Asami et al. 10.1038/s41598-021-01484-z
- An isotope ratio mass spectrometry‐based method for hydrogen isotopic analysis in sub‐microliter volumes of water: Application for multi‐isotope investigations of gases extracted from fluid inclusions A. Buikin et al. 10.1002/rcm.8923
- Paleotemperature reconstructions using speleothem fluid inclusion analyses from Hungary A. Demény et al. 10.1016/j.chemgeo.2020.120051
- Penultimate deglaciation Asian monsoon response to North Atlantic circulation collapse J. Wassenburg et al. 10.1038/s41561-021-00851-9
- Holocene Hydroclimate Variability Along the Southern Patagonian Margin (Chile) Reconstructed from Cueva Chica Speleothems C. Nehme et al. 10.2139/ssrn.4172978
- Clumped isotope reordering kinetics in strontianite and witherite: Experiments and first-principles simulations Z. Sun et al. 10.1016/j.epsl.2023.118467
- Challenges in the Direct Determination of 17Oexcess in Microliter Amount of Water Extracted From Speleothem Fluid Inclusions S. Affolter & M. Leuenberger 10.3389/feart.2021.612436
- Fingerprinting Kinetic Isotope Effects and Diagenetic Exchange Reactions Using Fluid Inclusion and Dual‐Clumped Isotope Analysis P. Staudigel et al. 10.1029/2022GC010766
- A comparison of isotope ratio mass spectrometry and cavity ring‐down spectroscopy techniques for isotope analysis of fluid inclusion water S. de Graaf et al. 10.1002/rcm.8837
- Constraints for precise and accurate fluid inclusion stable isotope analysis using water-vapour saturated CRDS techniques T. Weissbach et al. 10.1016/j.chemgeo.2022.121268
- Holocene hydroclimate variability along the Southern Patagonian margin (Chile) reconstructed from Cueva Chica speleothems C. Nehme et al. 10.1016/j.gloplacha.2023.104050
- Temperature Reconstructions Using Speleothems A. Meckler et al. 10.2138/gselements.17.2.101
- Analytical Artefacts Preclude Reliable Isotope Ratio Measurement of Internal Water in Coral Skeletons S. de Graaf et al. 10.1111/ggr.12445
- Last glacial millennial-scale hydro-climate and temperature changes in Puerto Rico constrained by speleothem fluid inclusion <i>δ</i><sup>18</sup>O and <i>δ</i><sup>2</sup>H values S. Warken et al. 10.5194/cp-18-167-2022
18 citations as recorded by crossref.
- Characterization and Correction of Evaporative Artifacts in Speleothem Fluid Inclusion Isotope Analyses as Applied to a Stalagmite From Borneo A. Fernandez et al. 10.1029/2023GC010857
- Variability in effective moisture inferred from inclusion fluid δ18O and δ2H values in a central Sierra Nevada stalagmite (CA) B. Wortham et al. 10.1016/j.quascirev.2022.107399
- A geochemical study of the Sweet Home mine, Colorado Mineral Belt, USA: formation of deep hydrothermal vein–type molybdenum greisen and base metal mineralization M. Stoltnow et al. 10.1007/s00126-022-01102-6
- Oxygen isotopes of the Japanese stalagmites as global and local paleoclimate proxies A. Kano et al. 10.1111/iar.12491
- Last glacial temperature reconstructions using coupled isotopic analyses of fossil snails and stalagmites from archaeological caves in Okinawa, Japan R. Asami et al. 10.1038/s41598-021-01484-z
- An isotope ratio mass spectrometry‐based method for hydrogen isotopic analysis in sub‐microliter volumes of water: Application for multi‐isotope investigations of gases extracted from fluid inclusions A. Buikin et al. 10.1002/rcm.8923
- Paleotemperature reconstructions using speleothem fluid inclusion analyses from Hungary A. Demény et al. 10.1016/j.chemgeo.2020.120051
- Penultimate deglaciation Asian monsoon response to North Atlantic circulation collapse J. Wassenburg et al. 10.1038/s41561-021-00851-9
- Holocene Hydroclimate Variability Along the Southern Patagonian Margin (Chile) Reconstructed from Cueva Chica Speleothems C. Nehme et al. 10.2139/ssrn.4172978
- Clumped isotope reordering kinetics in strontianite and witherite: Experiments and first-principles simulations Z. Sun et al. 10.1016/j.epsl.2023.118467
- Challenges in the Direct Determination of 17Oexcess in Microliter Amount of Water Extracted From Speleothem Fluid Inclusions S. Affolter & M. Leuenberger 10.3389/feart.2021.612436
- Fingerprinting Kinetic Isotope Effects and Diagenetic Exchange Reactions Using Fluid Inclusion and Dual‐Clumped Isotope Analysis P. Staudigel et al. 10.1029/2022GC010766
- A comparison of isotope ratio mass spectrometry and cavity ring‐down spectroscopy techniques for isotope analysis of fluid inclusion water S. de Graaf et al. 10.1002/rcm.8837
- Constraints for precise and accurate fluid inclusion stable isotope analysis using water-vapour saturated CRDS techniques T. Weissbach et al. 10.1016/j.chemgeo.2022.121268
- Holocene hydroclimate variability along the Southern Patagonian margin (Chile) reconstructed from Cueva Chica speleothems C. Nehme et al. 10.1016/j.gloplacha.2023.104050
- Temperature Reconstructions Using Speleothems A. Meckler et al. 10.2138/gselements.17.2.101
- Analytical Artefacts Preclude Reliable Isotope Ratio Measurement of Internal Water in Coral Skeletons S. de Graaf et al. 10.1111/ggr.12445
- Last glacial millennial-scale hydro-climate and temperature changes in Puerto Rico constrained by speleothem fluid inclusion <i>δ</i><sup>18</sup>O and <i>δ</i><sup>2</sup>H values S. Warken et al. 10.5194/cp-18-167-2022
Latest update: 17 Apr 2024
Short summary
The oxygen isotopic ratio of water in fluid inclusions in speleothems is an important proxy for the changes in past hydroclimate and temperatures. This isotopic ratio, however, may be affected by isotopic exchange between the water and the host calcite. Here we evaluate this exchange reaction based on a laboratory experiment. We demonstrated that the exchange was detectable but not significant for temperature reconstruction, likely because the reaction occurred only with a thin calcite layer.
The oxygen isotopic ratio of water in fluid inclusions in speleothems is an important proxy for...
